Well, if aesthetic interface is really important, there is PotPlayer, that is fully skinnable, and has almost everything MPC-HC has except decent subtitle engine that is usable with DXVA. There is a thread about it here in doom9 too, therefore I think it is a valid alternative video player for those who want shiny GUI.
MPC-HC itself has their own share of problems that isn't related to the GUI I would like the developers to work on them. As of build 2903, the IQ for EVR custom presenter is still not up to par with madVR for example.
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