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Deblocking should definitely always be done before other processing. It's up to you if you want to deinterlace or not, but if so that should always be next. Then you can denoise, color correct, etc. QTGMC includes deblocking and denoising, though, so doubling up might be why it looks like overkill.
If the videos still exist, it'll be a giant pain in the ass to do it all over again but the result will be worth it in the end. Hopefully you can let most of them go overnight and at work once the workflow is ready.
It might be a decent time to edit them down as long as you're touching with them all now. I hate to say it, but most family and wedding video never gets revisited because of so many easy to remove lulls.
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