I had a similar problem after upgrading to XP Home & Win 2k Pro... No matter what version DVD2AVI I used, I would get that 'unrecognized exception' error. Eventually, I replaced mpeg2dec.dll, re-created my .d2v project, and I was back in business!
I dont know why replacing mpeg2dec.dll fixed the problem, maybe it had become corrupt after upgrading Windows?... Anyway, I'd delete all the .dll's you are currently using, download them (possibly from another source), and try again.
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